Share:


Preparation and characterization of mesoporous cerium oxide for toxic As(V) removal: performance and mechanistic studies

    Uttam Kumar Sahu Affiliation
    ; Sandip Mandal Affiliation
    ; Sumanta Sahu Affiliation
    ; Narayan Gouda Affiliation
    ; Raj Kishore Patel Affiliation

Abstract

In the present work, the adsorption of carcinogenic pentavalent arsenic (As(V)) from an aqueous solution was studied using mesoporous cerium oxide (MCO). The MCO was synthesized in the precipitation process and confirmed by FT-IR, SEM-EDX, XRD, and BET instrumental techniques. Batch adsorption showed that 95% of As(V) was removed in the optimum conditions of 0.60 g/L adsorbent dose, 10 mg/L initial concentration, time 30 min, and pH 3. Pseudo-secondorder kinetics and the Langmuir isotherm model were fitted to the experimental data. The MCO had a high surface area of 191.97 m2/g and a maximum adsorption capacity of 58.25 mg/g at pH 3. MCO could be able to remove 88% and 82% in the first and second cycles after being desorbed with 0.1 M NaOH solution. The Zeta potential and FTIR studies suggested that electrostatic attraction and ligand exchange mechanisms were responsible for As(V) adsorption.

Keyword : mesoporous cerium oxide, As(V), adsorption, desorption and removal

How to Cite
Sahu, U. K., Mandal, S., Sahu, S., Gouda, N., & Patel, R. K. (2022). Preparation and characterization of mesoporous cerium oxide for toxic As(V) removal: performance and mechanistic studies. Journal of Environmental Engineering and Landscape Management, 30(2), 321-330. https://doi.org/10.3846/jeelm.2022.16749
Published in Issue
Jun 14, 2022
Abstract Views
396
PDF Downloads
289
Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

References

Başkan, M. B., Pala, A., & Türkman, A. (2010). Arsenate removal by coagulation using iron salts and organic polymers. Ekoloji, 74(19), 69–76. https://doi.org/10.5053/ekoloji.2010.7410

Basu, T., & Ghosh, U. C. (2013). Nano-structured iron(III)-cerium(IV) mixed oxide: Synthesis, characterization and arsenic sorption kinetics in the presence of co-existing ions aiming to apply for high arsenic groundwater treatment. Applied Surface Science, 283, 471–481. https://doi.org/10.1016/j.apsusc.2013.06.132

Basu, T., Nandi, D., Sen, P., & Chand, U. (2013). Equilibrium modeling of As (III, V) sorption in the absence / presence of some groundwater occurring ions by iron (III)– cerium (IV) oxide nanoparticle agglomerates: A mechanistic approach of surface interaction. Chemical Engineering Journal, 228, 665–678. https://doi.org/10.1016/j.cej.2013.05.037

Benramdane, L., Accominotti, M., Fanton, L., Malicier, D., & Vallon, J. J. (1999). Arsenic speciation in human organs following fatal arsenic trioxide poisoning–A case report. Clinical Chemistry, 45(2), 301–306. https://doi.org/10.1093/clinchem/45.2.301

Chen, B., Zhu, Z., Hong, J., Wen, Z., Ma, J., Qiu, Y., & Chen, J. (2014). Nanocasted synthesis of ordered mesoporous cerium iron mixed oxide and its excellent performances for As(v) and Cr(vi) removal from aqueous solutions. Dalton Transactions, 43, 10767–10777. https://doi.org/10.1039/C4DT01101E

Chen, Bo, Zhu, Z., Guo, Y., Qiu, Y., & Zhao, J. (2013). Facile synthesis of mesoporous Ce-Fe bimetal oxide and its enhanced adsorption of arsenate from aqueous solutions. Journal of Colloid and Interface Science, 398, 142–151. https://doi.org/10.1016/j.jcis.2013.02.004

Chen, J., Patil, S., Seal, S., & McGinnis, J. F. (2006). Rare earth nanoparticles prevent retinal degeneration induced by intracellular peroxides. Nature Nanotechnology, 1, 142–150. https://doi.org/10.1038/nnano.2006.91

Chen, W., Parette, R., Zou, J., Cannon, F. S., & Dempsey, B. A. (2007). Arsenic removal by iron-modified activated carbon. Water Research, 41, 1851–1858. https://doi.org/10.1016/j.watres.2007.01.052

Dai, S., Wang, N., Qi, C., Wang, X., Ma, Y., Yang, L., Liu, X., Huang, Q., Nie, C., Hu, B., & Wang, X. (2019). Preparation of core-shell structure Fe3O4@C@MnO2 nanoparticles for efficient elimination of U(VI) and Eu(III) ions. Science of the Total Environment, 685, 196–199. https://doi.org/10.1016/j.scitotenv.2019.06.292

Duman, O., Özcan, C., Polat, T. G., & Tunç, S. (2019). Carbon nanotube-based magnetic and non-magnetic adsorbents for the high-efficiency removal of diquat dibromide herbicide from waterwater: OMWCNT, OMWCNT-Fe3O4 and OMWCNT-κ-carrageenan-Fe3O4 nanocomposites. Enviromental Pollution, 244, 723–732. https://doi.org/10.1016/j.envpol.2018.10.071

Duman, O., Polat, T. G., Diker, C. Ö., & Tunç, S. (2020). Agar/κ-carrageenan composite hydrogel adsorbent for the removal of Methylene Blue from water. International Journal of Biological Macromolecules, 160, 823–835. https://doi.org/10.1016/j.ijbiomac.2020.05.191

Duman, O., Tunç, S., & Gürkan Polat, T. (2015). Adsorptive removal of triarylmethane dye (Basic Red 9) from aqueous solution by sepiolite as effective and low-cost adsorbent. Microporous and Mesoporous Materials, 210, 176–184. https://doi.org/10.1016/j.micromeso.2015.02.040

Duman, O., Tunç, S., Bozoğlan, B. K., & Polat, T. G. (2016a). Removal of triphenylmethane and reactive azo dyes from aqueous solution by magnetic carbon nanotube-κ-carrageenan-Fe3O4 nanocomposite. Journal of Alloys and Compounds, 687, 370–383. https://doi.org/10.1016/j.jallcom.2016.06.160

Duman, O., Tunç, S., Polat, T. G., & Bozoğlan, B. K. (2016b). Synthesis of magnetic oxidized multiwalled carbon nanotube-κ-carrageenan-Fe3O4 nanocomposite adsorbent and its application in cationic Methylene Blue dye adsorption. Carbohydrate Polymers, 147, 79–88. https://doi.org/10.1016/j.carbpol.2016.03.099

Freundlich, H. (1906). User die adsorption in losungen [Adsorption in solution]. The Journal of Physical Chemistry, 57, 384–470. https://doi.org/10.1515/zpch-1907-5723

Gerente, C., Andres, Y., McKay, G., & Le Cloirec, P. (2010). Removal of arsenic(V) onto chitosan: From sorption mechanism explanation to dynamic water treatment process. Chemical Engineering Journal, 158, 593–598. https://doi.org/10.1016/j.cej.2010.02.005

Guan, X., Dong, H., Ma, J., & Jiang, L. (2009). Removal of arsenic from water: Effects of competing anions on As(III) removal in KMnO4-Fe(II) process. Water Research, 43, 3891–3899. https://doi.org/10.1016/j.watres.2009.06.008

Hu, B., Ai, Y., Jin, J., Hayat, T., Alsaedi, A., Zhuang, L., & Wang, X. (2020). Efficient elimination of organic and inorganic pollutants by biochar and biochar-based materials. Biochar, 2, 47–64. https://doi.org/10.1007/s42773-020-00044-4

Huo, L., Zhao, S., Shi, B., Wang, H., & He, S. (2021). Bacterial community change and antibiotic resistance promotion after exposure to sulfadiazine and the role of UV/H2O2-GAC treatment. Chemosphere, 283, 131214. https://doi.org/10.1016/j.chemosphere.2021.131214

Kim, J., & Benjamin, M. M. (2004). Modeling a novel ion exchange process for arsenic and nitrate removal. Water Research, 38, 2053–2062. https://doi.org/10.1016/j.watres.2004.01.012

Kim, Y., Kim, C., Choi, I., Rengaraj, S., & Yi, J. (2004). Arsenic removal using mesoporous alumina prepared via a templating method. Environmental Science & Technology, 38, 924–931. https://doi.org/10.1021/es0346431

Kundu, S., & Gupta, A. K. (2006). Adsorptive removal of As(III) from aqueous solution using iron oxide coated cement (IOCC): Evaluation of kinetic, equilibrium and thermodynamic models. Separation and Purification Technology, 51, 165–172. https://doi.org/10.1016/j.seppur.2006.01.007

Langmuir, I. (1916). The conctitution and fundamental properties of solids and liquids. Journal of American Chemical Society, 38, 2221–2295. https://doi.org/10.1021/ja02268a002

Li, R., Li, Q., Gao, S., & Shang, J. K. (2012). Exceptional arsenic adsorption performance of hydrous cerium oxide nanoparticles: Part A. Adsorption capacity and mechanism. Chemical Engineering Journal, 185–186, 127–135. https://doi.org/10.1016/j.cej.2012.01.061

Liang, L., Xi, F., Tan, W., Meng, X., Hu, B., & Wang, X. (2021). Review of organic and inorganic pollutants removal by biochar and biochar-based composites. Biochar, 3(3), 255–281. https://doi.org/10.1007/s42773-021-00101-6

Liu, F., Hua, S., Wang, C., Qiu, M., Jin, L., & Hu, B. (2021a). Adsorption and reduction of Cr(VI) from aqueous solution using cost-effective caffeic acid functionalized corn starch. Chemosphere, 279, 130539. https://doi.org/10.1016/j.chemosphere.2021.130539

Liu, X., Pang, H., Liu, X., Li, Q., Zhang, N., Mao, L., Qiu, M., Hu, B., Yang, H., & Wang, X. (2021b). Orderly porous covalent organic frameworks-based materials: Superior adsorbents for pollutants removal from aqueous solutions. The Innovation, 2(1), 100076. https://doi.org/10.1016/j.xinn.2021.100076

Mahmood, T., Din, S. U., Naeem, A., Mustafa, S., Waseem, M., & Hamayun, M. (2012). Adsorption of arsenate from aqueous solution on binary mixed oxide of iron and silicon. Chemical Engineering Journal, 192, 90–98. https://doi.org/10.1016/j.cej.2012.03.048

Mou, F., Guan, J., Ma, H., Xu, L., & Shi, W. (2012). Magnetic iron oxide chestnutlike hierarchical nanostructures: Preparation and their excellent arsenic removal capabilities. ACS Applied Materials and Interfaces, 4, 3987–3993. https://doi.org/10.1021/am300814q

Nakamoto, K. (1978). Infrared and raman spectra of inorganic and coordination compounds (3rd ed.). John Wiley.

Pawlak, Z., Zak, S., & Zablocki, L. (2006). Removal of hazardous metals from groundwater by reverse osmosis. Polish Journal of Environmental Studies, 15(4), 579–583.

Ren, Z., Zhang, G., & Chen, P. J. (2011). Adsorptive removal of arsenic from water by an iron-zirconium binary oxide adsorbent. Journal of Colloid and Interface Science, 358, 230–237. https://doi.org/10.1016/j.jcis.2011.01.013

Sahu, U. K., Sahu, M. K., Mohapatra, S. S., & Patel, R. K. (2016). Removal of As(V) from aqueous solution by Ce-Fe bimetal mixed oxide. Journal of Environmental Chemical Engineering, 4, 2892–2899. https://doi.org/10.1016/j.jece.2016.05.041

Sahu, U. K., Sahu, S., Mahapatra, S. S., & Patel, R. K. (2017). Cigarette soot activated carbon modified with Fe3O4 nanoparticles as an effective adsorbent for As(III) and As(V): Material preparation, characterization and adsorption mechanism study. Journal of Molecular Liquids, 243, 395–405. https://doi.org/10.1016/j.molliq.2017.08.055

Sahu, U. K., Sahu, S., Mahapatra, S. S., & Patel, R. K. (2019). Synthesis and characterization of magnetic bio-adsorbent developed from Aegle marmelos leaves for removal of As(V) from aqueous solutions. Environmental Science and Pollution Research, 26, 946–958. https://doi.org/10.1007/s11356-018-3643-1

Selvi, N., Padmanathan, N., Dinakaran, K., & Sankar, S. (2014). Effect of ZnO, SiO2 dual shells on CeO2 hybrid core–shell nanostructures and their structural, optical and magnetic properties. RSC Advances, 4, 55745–55751. https://doi.org/10.1039/C4RA07705A

Shao, W., Li, X., Cao, Q., Luo, F., Li, J., & Du, Y. (2008). Adsorption of arsenate and arsenite anions from aqueous medium by using metal(III)-loaded amberlite resins. Hydrometallurgy, 91, 138–143. https://doi.org/10.1016/j.hydromet.2008.01.005

Smedley, P. L., & Kinniburgh, D. G. (2002). A review of the source, behaviour and distribution of arsenic in natural waters. Applied Geochemistry, 17, 517–568. https://doi.org/10.1016/S0883-2927(02)00018-5

Tang, D., & Zhang, G. (2016). Efficient removal of fluoride by hierarchical Ce–Fe bimetal oxides adsorbent: Thermodynamics, kinetics and mechanism. Chemical Engineering Journal, 283, 721–729. https://doi.org/10.1016/j.cej.2015.08.019

Uddin, M. T., Mozumder, M. S. I., Islam, M. A., Deowan, S. A., & Hoinkis, J. (2007). Nanofiltration membrane process for the removal of arsenic from drinking water. Chemical Engineering & Technology, 30(9), 1248–1254. https://doi.org/10.1002/ceat.200700169

Wen, Z., Dai, C., Zhu, Y., & Zhang, Y. (2014). Arsenate removal from aqueous solutions using magnetic mesoporous iron manganese bimetal. RSC Advances, 5, 4058–4068. https://doi.org/10.1039/C4RA09746G

Wu, Z., & Zhao, D. (2011). Ordered mesoporous materials as adsorbents. Chemical Communications, 47, 3332–3338. https://doi.org/10.1039/c0cc04909c

Wu, Z., Li, W., Webley, P. A., & Zhao, D. (2012). General and controllable synthesis of novel mesoporous magnetic iron oxide@carbon encapsulates for efficient arsenic removal. Advanced Materials, 24, 485–491. https://doi.org/10.1002/adma.201103789

Zhang, G., Ren, Z., Zhang, X., & Chen, J. (2013). Nanostructured iron(III)-copper(II) binary oxide: A novel adsorbent for enhanced arsenic removal from aqueous solutions. Water Research, 47, 4022–4031. https://doi.org/10.1016/j.watres.2012.11.059

Zhang, Y., Dou, X., Zhao, B., Yang, M., Takayama, T., & Kato, S. (2010). Removal of arsenic by a granular Fe-Ce oxide adsorbent: Fabrication conditions and performance. Chemical Engineering Journal, 162, 164–170. https://doi.org/10.1016/j.cej.2010.05.021

Zholobak, N. M., Ivanov, V. K., Shcherbakov, A. B., Shaporev, A. S., Polezhaeva, O. S., Baranchikov, A. Y., Spivak, N. Y., & Tretyakov, Y. D. (2011). UV-shielding property, photocatalytic activity and photocytotoxicity of ceria colloid solutions. Journal of Photochemistry and Photobiology B: Biology, 102, 32–38. https://doi.org/10.1016/j.jphotobiol.2010.09.002

Zhu, Y., He, X., Xu, J., Fu, Z., Wu, S., Ni, J., & Hu, B. (2021). Insight into efficient removal of Cr(VI) by magnetite immobilized with Lysinibacillus sp. JLT12: Mechanism and performance. Chemosphere, 262, 127901. https://doi.org/10.1016/j.chemosphere.2020.127901