Comparison of different adsorbents, cellulose aerogel, devulcanized rubber granules and pyrolyzed sewage sludge granules, for dye removal from contaminated water
Abstract
The release of dyes used in the textile industry into the natural environment causes unwanted negative effects due to the carcinogenic, mutagenic or even teratogenic properties of the dyes. Based on their chemical composition, dyes are divided into anionic, cationic and non-ionic dyes. In this work, the physical method of wastewater treatment – adsorption – was studied. This is a method in which various natural substances called sorbents are used. Materials used in the adsorption process should be nontoxic, environmentally friendly, cheap, and their use should not cause secondary pollution. The idea of using sorbents made from waste in experimental studies, which can even be used several times in the adsorption process, promotes the sustainable use of resources. The study compared different sorbents: aerogel, devulcanized rubber granules and sewage sludge. It was found that the highest values of adsorption efficiency were characterized by sewage sludge granules that were pyrolyzed at 500 °C. Using 500 °C pyrolysis sewage sludge, the adsorption efficiency reached 28.14–53.73%. Granules made from devulcanized car tire rubber had the lowest adsorption efficiency values: the adsorption efficiency value reached 12.92%. The adsorption efficiency values of the aerogel synthesized from paper waste ranged from 28.21 to 38.07%.
Article in Lithuanian.
Skirtingų adsorbentų, celiuliozės aerogelio, devulkanizuotos gumos granulių ir pirolizuotų nuotekų dumblo granulių naudojimo dažikliams šalinti iš užteršto vandens palyginimas
Santrauka
Tekstilės pramonėje naudojamų dažiklių patekimas į gamtinę aplinką kelia nepageidaujamą neigiamą poveikį dėl dažiklių kancerogeninių, mutageninių ar net teratogeninių savybių. Remiantis chemine sudėtimi dažikliai yra skirstomi į anijoninius, katijoninius ir nejoninius dažiklius. Šiame darbe buvo tirtas fizikinis gamybinių nuotekų valymo būdas – adsorbcija. Tai metodas, kurio metu yra naudojamos įvairios prigimties medžiagos, vadinamos sorbentais. Adsorbcijos procese naudojamos medžiagos turėtų būti netoksiškos, draugiškos aplinkai, pigios, jų naudojimas neturėtų sukelti antrinės taršos. Eksperimentiniuose tyrimuose naudojamų iš atliekų pagamintų sorbentų, kuriuos adsorbcijos procese galima panaudoti net kelis kartus, idėja skatina tvarų išteklių naudojimą. Tyrime palyginti skirtingi sorbentai: iš popieriaus susintetintas aerogelis, devulkanizuotos gumos granulės ir nuotekų dumblo granulės. Nustatyta, jog aukščiausiomis adsorbcijos efektyvumo vertėmis pasižymėjo nuotekų dumblo granulės, kurios buvo pirolizuotos 500 °C temperatūroje. Naudojant 500 °C pirolizės nuotekų dumblo granules adsorbcijos efektyvumas siekė 28,14–53,73 %. Žemiausiomis adsorbcijos efektyvumo vertėmis pasižymėjo iš devulkanizuotos automobilių padangų gumos pagamintos granulės: adsorbcijos efektyvumo vertė siekė 12,92 %. Iš popieriaus atliekų susintetinto aerogelio adsorbcijos efektyvumo vertės svyravo 28,21–38,07 % intervale.
Reikšminiai žodžiai: adsorbcija, aerogelis, dažikliai, devulkanizuotos gumos granulės, nuotekų dumblas, tekstilė.
Keyword : adsorption, aerogel, dyes, devulcanized rubber granules, sewage sludge, textile
This work is licensed under a Creative Commons Attribution 4.0 International License.
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